Sabrina the Teenage Witch was something that my mom had me watch when I was growing up, and it is super duper cheesy. However, it is really wholesome, and anytime that there is bad behavior, there's always a moral at the end of each episode, and it always helped you to develop good character traits and to avoid bad ones.
Daniel Tiger's Neighborhood and also Bluey, but one adult show for the older audiences that I wouldn't have kiddos watch is Bob's Burgers. I feel like it actually does have quite a few really good lessons that it teaches in the later seasons, not as much as in the first season, but there you go.
I've always loved the Magic School Bus as a kid. I think honestly that show is really great for kids and even adults because it like promotes like learning. You learn about something new in every episode, creativity, excitement about science and learning, and I just know that it's a really positive and clean show. So yeah, I think the Magic School Bus is really awesome and teaches great values.